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Regional Ksp Problem
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Posted:
Wed Apr 18, 2007 12:16 pm
by mathguy
OK, Number 34 on the regional test has me stumped. I got it right, but I'm not sure if my logic was correct or if I was just lucky. Can somebody walk me through it?
34. Solid AgNO3 is slowly added to a solution containint 0.0010 M each of NaCl and NaBr. What concentration of Br- would remain in solution when AgCl begins to precipitate? The solubility product constant for AgCl is 1.8*10^-10 and that of AgBr is 3.3*10^-13.
Correct answer is 1.8*10^-6
Thanks a lot!!!
Re: Regional Ksp Problem
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Posted:
Wed Apr 18, 2007 1:35 pm
by MisterC
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Posted:
Wed Apr 18, 2007 5:28 pm
by Kurt
And does anyone know how to do #39? That's the only one I skipped on the test (other than the faulty physics question, that is). I had no idea how to do it.
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Posted:
Wed Apr 18, 2007 5:52 pm
by bradp
I didn't take it in competition, but, after looking at the test, this is how my scores probably would have gone:
Biology: [unparseable or potentially dangerous latex formula]
Chemistry: [unparseable or potentially dangerous latex formula]
Physics: [unparseable or potentially dangerous latex formula]
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Posted:
Wed Apr 18, 2007 6:14 pm
by MisterC
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Posted:
Wed Apr 18, 2007 6:22 pm
by bradp
You're given two [unparseable or potentially dangerous latex formula] values at two different temperatures and asked to find the [unparseable or potentially dangerous latex formula] of the self-ionization of [unparseable or potentially dangerous latex formula]
Kw for the self-ionization of water is 1.13E-15 at 273 K and becomes 9.61E-14 at 333 K. Calculate [unparseable or potentially dangerous latex formula] for the self ionization of water.
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Posted:
Wed Apr 18, 2007 6:32 pm
by MisterC
You need two equations:
Delta G = Delta H -T Delta S
and dG = -RT ln(K)
so,
dH-TdS = -RTln(K)
and
ln(K) = -dH/R(1/T) + dS/R
That gets the equation into the form of y=mx+b
You can solve for dH given the two Kw and temps.
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Posted:
Thu Apr 19, 2007 12:39 am
by Kurt
Ah, I guess I didn't know the second equation. Thanks. :)
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Posted:
Thu Apr 19, 2007 4:02 pm
by bradp
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Posted:
Thu Apr 19, 2007 4:05 pm
by stupidityismygam
omg, bradp learned [unparseable or potentially dangerous latex formula]
WOOHOO
i am so proud of you, my little boy is growing up :)
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Posted:
Thu Apr 19, 2007 8:19 pm
by MisterC
That is cool. Where can I find how to LATEX??
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Posted:
Thu Apr 19, 2007 9:30 pm
by bradp
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Posted:
Thu Apr 19, 2007 9:57 pm
by MisterC
[unparseable or potentially dangerous latex formula]
Interesting!
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Posted:
Tue Jun 26, 2007 1:27 pm
by bradp
nevermiind